Preparation and Characterization of Zirconia-Coated Nanodiamonds as a Pt Catalyst Support for Methanol Electro-Oxidation
نویسندگان
چکیده
Zirconia-coated nanodiamond (ZrO₂/ND) electrode material was successfully prepared by one-step isothermal hydrolyzing from ND-dispersed ZrOCl₂·8H₂O aqueous solution. High-resolution transmission electron microscopy reveals that a highly conformal and uniform ZrO₂ shell was deposited on NDs by this simple method. The coating obtained at 90 °C without further calcination was mainly composed of monoclinic nanocrystalline ZrO₂ rather than common amorphous Zr(OH)₄ clusters. The ZrO₂/NDs and pristine ND powder were decorated with platinum (Pt) nanoparticles by electrodeposition from 5 mM chloroplatinic acid solution. The electrochemical studies indicate that Pt/ZrO₂/ND catalysts have higher electrocatalytic activity and better stability for methanol oxidation than Pt/ND catalysts in acid.
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